Table 1.

List of MOF-based luminescent chemodosimeters for H₂S.

MOF Formula	λex/λem (nm)	Dynamic Range	LOD 1	RT 2	Media	Real Sampe	Ref.
Zr6O4(OH)4(BDC-N3)6	334/436	0–4 mM	117 μM	180 s	HEPES buffer (10 mM, pH 7.4)	Live cells	[71]
Zr6O4(OH)4(BDC-NO2)6	334/436	0–4 mM	188 μM	460 s	HEPES buffer (10 mM, pH 7.4)	--	[72]
Zn4O(OH)4(BDC-N3)3	395/455	0–0.5 mM	28.3 μM	90 s	HEPES ethanol buffer (10 mM, pH 7.4)	--	[73]
Ce6O4(OH)4(BDC-N3)6	334/429	0–3.5 mM	12.2 μM	760 s	HEPES buffer (10 mM, pH 7.4)	--	[74]
Ce6O4(OH)4(BDC-NO2)6	334/429	0–3.5 mM	34.8 μM	480 s	HEPES buffer (10 mM, pH 7.4)	--	[74]
Al(OH)(IPA-N3)	330/405	0–0.06 mM	2.65 μM	420 s	HEPES buffer (10 mM, pH 7.4)	Live cells	[75]
Zr6O4(OH)4((NDC-(NO2)2)6	390/474	0.1–0.7 mM	20 μM	50 min	HEPES buffer (10 mM, pH 7.4)	Live cells	[76]
Al(OH)(BDC-N3)	315/425	0.2–1.6 μM	90.47 nM	60 s	HEPES buffer (10 mM, pH 7.4)	Live cells	[77]
Al3O4(OH)4(BDC-(NO2)2)6	345/527	0.1–0.6 mM	14.14 μM	40 min	HEPES buffer (10 mM, pH 7.4)	Live cells	[78]
Al3(O)(OH)(BDC-N3)3	343/460, 565	0.1–120 μM	100 nM	--	Hank’s balanced salt solution	Cell sample	[79]
Al(OH)(BDC-NO2)/poly(vinylidene fluoride)	396/466	0–0.1 mM	92.31 nM	--	PVDF membrane	Lake water	[80]
Cu(TCPP)[AlOH]2	419/602, 650	0–10 μM	16 nM	instant	BBS buffer (20 mM, pH 7.4)	Live cells	[81]
CuO@TO@UiO-66	510/~560	0–100 μM	0.51 μM	instant	Tris-HCl butter (20 mM, pH 7.4)	Live cells	[82]
Eu3+/Cu2+@UiO-66-(COOH)2	305/393, 615	0–625 μM	5.45 μM	30 s	HEPES buffer (10 mM, pH 7.4)	--	[83]
Eu3+/Ag+@UiO-66-(COOH)2	305/615	0–2.5 mM	23.53 μM	30 s	HEPES buffer (10 mM, pH 7.4)	Serum	[84]
Tb3+@[Cu(CPOC)2]	280/390, 544	0–1.6 mM	13.25 μM	2 min	HEPES buffer (10 mM, pH 7.4)	--	[85]
UiO-66-CH = CH2 Zr6O4(OH)4(BDC-CH = CH2)6	328/382	0–0.05 mM	6.46 μM	10 s	HEPES buffer (10 mM, pH 7.4)	Live cells	[86]
FeIII-MIL-88-NH2	333/~440	60–100 μM	10 μM	5 min	Aqueous solution	--	[87]

¹ LOD means limit of detection. ² RT means reaction time.