Table 1.
The research status on switching mechanism of memristive devices
Properties | Common items for all types | Cation devices | Anion devices | Dual ionic devices |
---|---|---|---|---|
Chemical composition | Ion migration or phase change |
Active metals, such as Ag, Cu Less active metals, such as Ti, Ta |
Oxygen ions or vacancies Other anions, such as nitrogen vacancies |
Both cation and anion |
Driving force |
Electric field Thermal effects (thermophoresis)20 Chemical potential gradient92 |
Nanobattery effect93 Interfacial energy minimization9 |
Relative role of field and temperature Thermodynamics2 |
Relative role of field and temperature Thermodynamics |
Filament morphology |
Filamentary Single and multiple filaments Dendrite-like filament45 Inverted or forward cone shape14 |
Chain of nanoparticles12 Inverted triangle crystalline13 Non-filamentary81 |
Non-filamentary94 Percolation path Filament rupture region |
Percolation path Filament rupture region |
Electron conduction mechanism |
Ohmic conduction Schottky emission Tunneling (direct or FN) |
SCLC model95 Quantum conductance96 |
P-F model, SCLC model97 Hopping (fixed-ranged, variable-ranged)98 TAT model |
Trap Assisted Tunneling (TAT) model |
Switching dynamics |
Redox reaction Nucleation99 Microscopic picture of switching |
Filament growth direction Growth dynamics14 Filament dissolution |
Oxygen vacancy generation in the bulk Interstitial oxygen ion migration Dynamic motion of oxygen |
Migration dynamics of cations and anions Reaction of cations and anions |
Non-italicized indicates the conclusive findings, and italicized represents arguments not fully conclusive yet