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. 2019 Aug 1;10:3453. doi: 10.1038/s41467-019-11411-6

Table 1.

The research status on switching mechanism of memristive devices

Properties Common items for all types Cation devices Anion devices Dual ionic devices
Chemical composition Ion migration or phase change

Active metals, such as Ag, Cu

Less active metals, such as Ti, Ta

Oxygen ions or vacancies

Other anions, such as nitrogen vacancies

Both cation and anion
Driving force

Electric field

Thermal effects (thermophoresis)20

Chemical potential gradient92

Nanobattery effect93

Interfacial energy minimization9

Relative role of field and temperature

Thermodynamics2

Relative role of field and temperature

Thermodynamics

Filament morphology

Filamentary

Single and multiple filaments

Dendrite-like filament45

Inverted or forward cone shape14

Chain of nanoparticles12

Inverted triangle crystalline13

Non-filamentary81

Non-filamentary94

Percolation path

Filament rupture region

Percolation path

Filament rupture region

Electron conduction mechanism

Ohmic conduction

Schottky emission

Tunneling (direct or FN)

SCLC model95

Quantum conductance96

P-F model, SCLC model97

Hopping (fixed-ranged, variable-ranged)98 TAT model

Trap Assisted Tunneling (TAT) model
Switching dynamics

Redox reaction

Nucleation99

Microscopic picture of switching

Filament growth direction

Growth dynamics14

Filament dissolution

Oxygen vacancy generation in the bulk

Interstitial oxygen ion migration

Dynamic motion of oxygen

Migration dynamics of cations and anions

Reaction of cations and anions

Non-italicized indicates the conclusive findings, and italicized represents arguments not fully conclusive yet