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. 2019 Jul 8;11(7):1160. doi: 10.3390/polym11071160

Table 4.

Typical additives used for PS membrane fabrication with their conditions.

PS Solvent/Non-Solvent Additive Morphology Configuration Ref.
PS (Mw = 30 kDa) 1. NMP/water
2. DMAc/water
PVP (Mw = 24, 40 and 360 kDa) Pore density PS/NMP/PVP: 2.6 × 109–9.8 × 109 Flat-sheet [43]
PS/DMAc/PVP: 5.5 × 109–10.5 × 109
Pore size (nm) PS/NMP/PVP: 3.0–3.62
PS/DMAc/PVP: 3.21–3.88
PS (Udel 1700) DMAc/water PVP (K15, Janssen Chemical) Flat-sheet: macrovoids. hollow fibers: large pores on the external surface with a spongy structure underneath. Flat-sheet and hollow fibers [128]
PS (Mn = 26 kDa) NMP/water 1. PEG, (Mn = 8 kDa)
2. PVP (Mn = 8 and 40 kDa)
Pore size (nm) PS: 59–61.8 Flat-sheet [129]
PS+PEG: 113.8
PS+PVP: 60.6–75
PS (Ultrason S6010) NMP/water Tetronic- 1107 Pore size (nm) 7–13 Flat-sheet [111]
PS (Mw = 77–83 kDa) NMP/water 1. graphene oxide (GO) nanosheets
2. Janus graphene oxide (Janus GO) nanosheets
Pore size (nm): PS: 11.21 Flat-sheet [80]
GO/PS: 15.82–19.67
JanusGO/PS: 18.50–21.01
Thickness (μm): 200
PS 1. NMP/water
2. DMAc/water
polyethylene glycol (PEG), TiO2 Molecular weight cut-off (MWCO) <600 Da Flat-sheet [81]
PS (Ultrason S 6010) DMF/water 1. SiO2 nanoparticle
2. Polydopamine (PDA)
Root-mean-square (RMS) (nm) PS: ~30 Flat-sheet [38]
PS/PDA: ~210
PS/SiO2: ~92
PS/SiO2/PDA: ~89
PS (Mn = 22 kDa) DMAc/water 1.Zn, Al-NO3LDH;
2. Trimethylsilylchlorosulfonate
Thickness (μm): 100 Flat-sheet [39]
PS (MW = 75 kDa) NMP/water 1. PEG (MW = 4 kDa);
2. Al2O3 nanoparticle
RMS (nm) PS: ~69 Flat-sheet [40]
PS/Al2O3: ~96–119
PS (Mw = 58 kDa) DMAc/water 1. Reduced graphene (rGO) Thickness (μm) CMPS: 20–25 Flat-sheet [33]
CMPS/rGO: 22–30