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. 2019 Jul 5;9(7):258. doi: 10.3390/biom9070258

Figure 8.

Figure 8

Thermal decomposition of 1,2-dioxetane by concerted (A) and diradical (B) mechanisms. In (A), the concerted mechanism involves the simultaneous cleavage of oxygen-oxygen and carbon-carbon bonds. In (B), diradical mechanism contains the cleavage of the oxygen-oxygen bond, resulting in the formation of diradical, followed by the cleavage of the carbon-carbon bond. Both mechanisms result in the formation of triplet exited carbonyl and ground state carbonyl.