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. 2019 Jul 2;4(7):11522–11531. doi: 10.1021/acsomega.9b01130

Table 1. Effect of Metal Co-catalyst on the Reduction of n-Heptylbenzene.

2.

entry catalyst additive 1a/2aa (mol/mol)
1 10% Pt/C   no reaction
2 10% Pt/C Fe 0/100 (98)b
3 10% Pt/C Zn 76/24
4 10% Pt/C Co 89/11
5 10% Pt/C Ni, Cr, Cu, Al, or Mg no reaction
6 10% Pt/C FeO 33/67
7 10% Pt/C Fe2O3 25/75
8 10% Pd/C Fe no reaction
9 10% Rh/C Fe no reaction
10   Fe no reaction
11c 10% Pt/C Fe 47/53
12d 10% Pt/C Fe no reaction
13e 10% Pt/C Fe 0/100 (97)b
a

Ratio was determined by 1H NMR.

b

Isolated yield.

c

At 80 °C.

d

At 50 °C.

e

7.4 mmol of 1a (1.3 g) was used as a substrate.