Table 1. Effect of Metal Co-catalyst on the Reduction of n-Heptylbenzene.
| entry | catalyst | additive | 1a/2aa (mol/mol) |
|---|---|---|---|
| 1 | 10% Pt/C | no reaction | |
| 2 | 10% Pt/C | Fe | 0/100 (98)b |
| 3 | 10% Pt/C | Zn | 76/24 |
| 4 | 10% Pt/C | Co | 89/11 |
| 5 | 10% Pt/C | Ni, Cr, Cu, Al, or Mg | no reaction |
| 6 | 10% Pt/C | FeO | 33/67 |
| 7 | 10% Pt/C | Fe2O3 | 25/75 |
| 8 | 10% Pd/C | Fe | no reaction |
| 9 | 10% Rh/C | Fe | no reaction |
| 10 | Fe | no reaction | |
| 11c | 10% Pt/C | Fe | 47/53 |
| 12d | 10% Pt/C | Fe | no reaction |
| 13e | 10% Pt/C | Fe | 0/100 (97)b |
Ratio was determined by 1H NMR.
Isolated yield.
At 80 °C.
At 50 °C.
7.4 mmol of 1a (1.3 g) was used as a substrate.
