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. Author manuscript; available in PMC: 2020 Aug 7.
Published in final edited form as: J Am Chem Soc. 2019 Jul 29;141(31):12388–12396. doi: 10.1021/jacs.9b05850

Scheme 4.

Scheme 4.

DFT-Optimized Stereochemical Models of Enantiodifferentiative H-Atom Abstraction by [Co(P4)] and [Co(P5)]a

a See the Supporting Information for movies of the major pathways leading to the enantiodifferentiative HAA and stereorentive RS by [Co(P4)] and [Co(P5)].