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. Author manuscript; available in PMC: 2020 Aug 19.
Published in final edited form as: Angew Chem Int Ed Engl. 2019 Jul 17;58(34):11657–11660. doi: 10.1002/anie.201904102

Figure 3.

Figure 3

A. Diversity-oriented synthesis of dibenzylbutyrolactones 18–22 via α-alkylation. B. Chemoenzymatic synthesis of 23, (–)-polygamain (5), (–)-morelensin (6), (–)-austrobailignan I (3), and (–)-hernandin (24) via late-stage C–C coupling with 2-ODD-PH. *^Reaction conducted at 5 mM substrate concentration with pre-lysis OD600 = 30. ^Reaction conducted at 1.5 mM substrate concentration with pre-lysis OD600 = 30. #Reaction conducted at 4 mM substrate concentration with pre-lysis OD600 = 30.