. 2019 Jul 2;75(Pt 8):1084–1089. doi: 10.1107/S2056989019009022

Table 2. Intermolecular interactions (Å, °) in the crystal structure of the RZHCl salt and RZ.

Motif number	Symmetry Code	Possible involved interactions	Geometry
RZHCL
I	x, y, z	N1—H1A⋯Cl1	2.15, 154
		N2—H2⋯Cl1	2.35, 139
II	−x, + y, − z	N1—H1B⋯Cl1	2.14, 175
III	x, 1 + y, z	C6—H6⋯Cl1	2.60, 135
		S1⋯Cl1	3.340 (2)
IV	1 − x, 2 − y, 2 − z	C4—H4⋯F1	2.57, 147
V	x, − y, + z	C5⋯C2	3.289 (7)
		C6⋯C1	3.292 (7)
		C7⋯S1	3.456 (6)

RZ
I(a)	−x, 2 − y, 2 − z	N7—H7B⋯N6	1.89, 170
		N5—H5B⋯N8	2.03, 175
I(b)	1 − x, 1 − y, 2 − z	N3—H3B⋯N2	1.92, 167
		N1—H1B⋯N4	2.06, 170
II(a)	−x, 1 − y, 2 − z	N7—H7A⋯N1	2.14, 169
II(b)	1 − x, 1 − y, 2 − z	N3—H3A⋯N5	2.15, 171
III(a)	1 + x, −1 + y, z	N1—H1A⋯N8	2.49, 155
		N1—H1A⋯C25	2.77, 130
		S1⋯C31	3.336 (1)
		S1⋯C26	3.430 (1)
III(b)	−1 + x, y, z	N5—H5A⋯N4	2.53, 159
		N5—H5A⋯C9	2.75, 140
		C10⋯S3	3.372 (1)
		C15⋯S3	3.311 (1)
		C22—H22⋯F4	2.44, 164
IV(a)	−1 + x, y, z	C4—H4⋯F4	2.46, 161
IV(b)	1 + x, y, z	C20—H20⋯F12	2.41, 161
V(a)	−x, 2 − y, 1 − z	F1⋯F10	2.907 (1), 137, 107
V(b)	x, −1 + y, z	F3⋯F10	2.923 (1), 115, 120
		C27—H27⋯C2	2.81, 129
V(c)	−x, 2 − y, 1 − z	F9⋯F9	2.845 (1), 127, 127
V(d)	1 − x, 1 − y, 1 − z	F2⋯F5	2.954 (1), 143, 119
V(e)	1 − x, 2 − y, 1 − z	F6⋯F7	2.946 (1), 142, 111
V(f)	−x, 2 − y, 1 − z	F11⋯F9	3.071 (1), 129, 97
VI	x, y, z	C5⋯O2	3.179 (1)
		C7⋯C14	3.308 (1)
VII	x, y, z	C3—H3⋯S3	2.84, 145
VIII	x, y, z	C17⋯S4	3.460 (1)
		C23⋯C30	3.295 (1)
IX	x, y, z	C12—H12⋯C18	2.82, 124
		C12—H12⋯C23	2.80, 133

The normalized values of hydrogen atoms given by PARST (Nardelli, 1995 ▸) were used for the hydrogen-bonding (Taylor & Kennard, 1983 ▸) analysis.

Table 2. Inter­molecular inter­actions (Å, °) in the crystal structure of the RZHCl salt and RZ.