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. 2019 Jun 18;9(8):6766–6782. doi: 10.1021/acscatal.9b00963

Table 3. Tyrosyl Radicals in LmChdCa.

tyrosine residue accessible surface area (Å2) % modified (+46 Da)
Y61 0.1057 0.12
Y97 8.4632 0.00
Y102 19.4741 0.00
Y104 0.3495 0.00
Y113 1.3375 0.00
Y125 23.9246 0.00
Y135 16.1367 15.60
Y147 0.0000 56.04
Y160 1.4756 0.30
Y181 5.3286 0.80
Y198 16.2791 n.d.b
Y228 0.6343 0.00
a

A 30 μM portion of LmChdC, preincubated with excess MNP, was treated with 2.5 mM H2O2, and covalent modifications were identified using mass spectrometry.

b

Not detected.