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. 2019 May 25;141(23):9129–9133. doi: 10.1021/jacs.9b00941

Figure 2.

Figure 2

(a) Variable temperature (VT) 1H NMR spectra (500 MHz, CD2Cl2) of 22+ in the region of the triazolium protons (HTru, HTrc). (b) VT 1H NMR spectra (500 MHz, CD2Cl2) of 12+ in the regions of the triazolium protons (HTru, HTrc; left) and of the methylene protons in the pyrenyl tether of the macrocycle, adjacent to the dioxybenzene unit (HPya, HPyb; right). See Scheme 1 and SI for proton labeling.