Table 2.
Syntheses of Amino-Rocaglatesa
![]() |
Reagents and conditions: 6a (1.0 equiv), NaH (5.0 equiv), amine (3.0 equiv), THF (0.1-0.2 M), 15 min at −78 °C, rt, 30-120 min.
500 mg scale; 83% on 25 mg scale.
250 mg scale; 90% on 25 mg scale.
6a (1.0 equiv), NaH (8.0 equiv), amine salt (3.0 equiv), THF (0.1-0.2 M).