Table 1. Absorption and emission spectral data of the benzoporphyrins.
Compound | λ abs/nm (ε × 105/M–1 cm–1) | λ em/nm |
TPBP | 465 (5.3), 588 a , 626 a , 640 a , 698 a | 720, 787 |
Zn-TPBP | 461 (2.8), 607 a , 652 a | 658, 724 |
Co-TPBP | 446 (1.7), 595 a , 640 (0.8) | — b |
Ni-TPBP | 449 (2.2), 592 a , 644 (0.9) | — b |
Cu-TPBP | 449 (1.6), 463 (1.9), 601 (0.1), 648 (0.8) | — b |
Sn-TPBP | 430 (0.3), 466 (4.1), 612 a , 660 (0.9) | 665, 745 |
aDue to low absorption, the ε value could not be determined.
bNo emission peak was observed.