Table 12.
Temperature dependence of equilibrium constants
| [eq (16)] | ||||||||
|---|---|---|---|---|---|---|---|---|
| Debye-Hückel | Davies | |||||||
| A mk | ||||||||
| k | 1 | 2 | 3 | 1 | 2 | |||
| m | ||||||||
| 1(s) | −8403.5 | 41.863 | −0.096779 | −9418.4 | 48.746 | |||
| 2(x) | 51090 | −341.14 | .58804 | 54735 | −365.90 | |||
| 3(y) | 19373 | −122.81 | .19943 | 31465 | −202.88 | |||
| °C | 5 | 15 | 25 | 37.5 | 5 | 15 | 25 | 37.5 |
| Km | ||||||||
| Ks×07 | 2.338 ±0.058 |
2.535 ±0.044 |
2.561 ±0.048 |
2.375 ±0.057 |
2.289 ±0.058 |
2.505 ±0.044 |
2.534 ±0.048 |
2.328 ±0.057 |
| K x | 446 ±54 |
272 ±35 |
255 ±35 |
401 ±71 |
479 ±57 |
283 ±36 |
264 ±36 |
431 ±74 |
| Ky | 10.1 ± 1.7 |
6.62 ± 1.23 |
5.10 ±1.03 |
4.51 ± 1.44 |
9.69 ± 1.83 |
5.23 ± 1.29 |
3.67 ±0.98 |
3.28 ± 1.48 |