Table 4.

Parameters of the GEEK, i.e., α_ij and β_j, for All Elementary Reactions at Different Inert Volume Fractions

Elementary Reaction		Crowding Conditions
Formula	Parameters	0%	10%	20%	30%	40%	50%
$S+E\stackrel{k_{1,f}}{\to }ES$	β1,f	7.31 × 10−2	2.61 × 10−1	4.57 × 10−1	6.87 × 10−1	9.57 × 10−1	1.25
	αS,1,f	4.74 × 10−3	∗	3.22 × 10−3	7.22 × 10−3	6.95 × 10−3	3.23 × 10−3
	αE,1,f	1.07 × 10−2	1.89 × 10−2	9.67 × 10−3	8.07 × 10−3	1.23 × 10−2	∗
	αES,1,f	∗	1.34 × 10−2	∗	∗	∗	∗
	αP,1,f	∗	2.51 × 10−3	−3.47 × 10−3	∗	∗	2.42 × 10−3
$ES\stackrel{k_{1,b}}{\to }S+E$	β1,b	−1.48 × 10−2	−1.17 × 10−1	−2.80 × 10−1	−5.46 × 10−1	−1.03	−2.26
	αS,1,b	−2.94 × 10−3	−3.56 × 10−3	−4.53 × 10−3	−6.09 × 10−3	−8.33 × 10−3	−9.58 × 10−3
	αE,1,b	−1.90 × 10−4	1.71 × 10−3	6.47 × 10−4	3.32 × 10−3	∗	3.16 × 10−3
	αE,1,b	∗	3.46 × 10−3	∗	2.03 × 10−3	−1.22 × 10−3	∗
	αP,1,b	−2.94 × 10−3	−3.58 × 10−3	−4.52 × 10−3	−6.09 × 10−3	−8.33 × 10−3	−9.58 × 10−3
$ES\stackrel{k_{2,f}}{\to }P+E$	β2,f	−1.48 × 10−2	−1.17 × 10−1	−2.80 × 10−1	−5.46 × 10−1	−1.03	−2.26
	αS,2,f	−2.94 × 10−3	−3.56 × 10−3	−4.53 × 10−3	−6.09 × 10−3	−8.34 × 10−3	−9.58 × 10−3
	αE,2,f	−1.90 × 10−4	1.71 × 10−3	6.53 × 10−4	3.31 × 10−3	∗	3.13 × 10−3
	αES,2,f	∗	3.46 × 10−3	∗	2.01 × 10−3	1.20 × 10−3	∗
	αP,2,f	−2.94 × 10−3	−3.58 × 10−3	−4.52 × 10−3	−6.10 × 10−3	−8.34 × 10−3	−9.57 × 10−3
$P+E\stackrel{k_{2,b}}{\to }ES$	β2,b	6.88 × 10−2	2.54 × 10−1	4.58 × 10−1	6.85 × 10−1	9.52 × 10−1	1.25
	αS,2,b	∗	∗	2.29 × 10−3	∗	3.09 × 10−3	∗
	αE,2,b	∗	∗	1.05 × 10−2	∗	∗	∗
	αES,2,b	∗	∗	∗	−7.78 × 10−3	∗	∗
	αP,2,b	6.59 × 10−3	2.76 × 10−3	4.70 × 10−3	6.85 × 10−3	8.45 × 10−3	3.74 × 10−3

The asterisks denote GEEK parameters with a significance of p ≤ 0.05.