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Catalytic Defluoroalkylation: Scope of Unactivated Trifluoromethylaromatic Substratesa
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Reaction conditions: Ar–CF3 substrate (0.5 mmol), 3-buten-1-ol (2.5 mmol), P3 (2 mol %), potassium formate (1.5 mmol), thiophenol (10 mol %), DMSO (5.0 mL), blue light, 100 °C, 24 h, isolated yields given.
Reaction conducted with 2.5 mmol of potassium formate.
Reaction conducted at 23 °C.
Reaction conducted with 5.0 mmol of olefin.
