| Emf‒temperature coefficient, μV K‒1 | Entropy change, ΔS | Enthalpy change, ΔH | |||||||
|---|---|---|---|---|---|---|---|---|---|
| °C | Int | Abs48 & t48 | Abs69 & t48 | Abs69 & t68 | σm (μV) | J K‒1 mol‒1 | cal K‒1 mol‒1 | (J mol‒1)c | (cal mol‒1)d |
| 0 | 9.40 | 9.40 | 9.40 | 9.40 | 0.14 | 1.814(.027) | 0.433 (.006) | ‒196,147.4(11.8) | ‒46,880.3(2.8) |
| 3 | 0.37 | 0.37 | 0.37 | 0.36 | .11 | 0.069 (.022) | .017(.005) | ‒196,624.8(10.4) | ‒46,994.5(2.5) |
| 5 | ‒5.35 | ‒5.35 | ‒5.36 | ‒5.37 | .10 | ‒1.036 (.020) | ‒0.248(.004) | ‒196,930.1(9.9) | ‒47,067.4(2.2) |
| 10 | ‒18.60 | ‒18.61 | ‒18.61 | ‒18.63 | .06 | ‒3.595(.012) | ‒ 0.859(.003) | ‒197,647.1(7.7) | ‒47,238.8(2.0) |
| 15 | ‒30.35 | ‒30.36 | ‒30.36 | ‒30.39 | .04 | ‒5.864 (.008) | ‒1.402 (.002) | ‒198,295.0(6.6) | ‒47,393.6(1.7) |
| 18 | ‒36.68 | ‒36.70 | ‒36.70 | ‒36.72 | .04 | ‒7.086(.008) | ‒1.694 (.001) | ‒198,649.3(6.6) | ‒47,478.2(1.3) |
| 20 | ‒40.60 | ‒40.62 | ‒40.61 | ‒40.64 | .04 | ‒7.843 (.008) | ‒1.874 (.002) | ‒198,870.4(6.6) | ‒47,531.1(1.5) |
| 25 | ‒49.35 | ‒49.37 | ‒49.36 | ‒49.39 | .04 | ‒9.531 (.008) | ‒ 2.278(.002) | ‒199,370.3(6.6) | ‒47,650.5(1.6) |
| 28 | ‒53.88 | ‒53.90 | ‒53.89 | ‒53.92 | .04 | ‒10.404(.008) | ‒2.487 (.002) | ‒199,632.2(6.6) | ‒47,713.1(1.7) |
| 30 | ‒56.60 | ‒56.62 | ‒56.61 | ‒56.63 | .04 | ‒10.929(.008) | ‒2.612(.002) | ‒199,790.7(6.7) | ‒47,750.8(1.7) |
| 35 | ‒62.35 | ‒62.37 | ‒62.35 | ‒62.37 | .06 | ‒12.036(.012) | ‒2.877 (.002) | ‒200,128.4(8.0) | ‒47,831.8(1.8) |
| 40 | ‒66.60 | ‒66.62 | ‒66.59 | ‒66.60 | .09 | ‒12.853(.018) | ‒3.072(.004) | ‒200,380.6(10.0) | ‒47,692.1(2.3) |
| 43.6a | ‒68.73 | ‒68.76 | ‒68.71 | ‒68.72 | .13 | ‒13.261 (.025) | ‒3.169(.007) | ‒200,506.4(12.3) | ‒47,927.0(3.3) |