Table 3.

Electromotive forces and thermodynamic data for standard cells of the saturated cadmium sulfate type

Temperature		Electromotive force, V				Gibbs energy change, ΔG
°C	Int	Abs48 & t48	Abs69 & t48	Abs69 & t68b	σm (μV)	(J mol‒1)c	(cal mol‒1)d
0	1.0186520	1.0189881	1.0189968	1.0189967	8.14	‒196,639.9(4.8)	‒46,998.0(1.1)
3	1.0186665	1.0190026	1.0190112	1.0190112	8.12	‒196,642.7(4.8)	‒46,998.6(1.1)
5	1.0186615	1.0189976	1.0190061	1.0190062	8.10	‒196,641.7(4.8)	‒46,998.4(1.1)
10	1.0186010	1.0189371	1.0189456	1.0189455	8.08.	‒196,630.0(4.8)	‒46,995.6(1.1)
15	1.0184780	1.0188141	1.0188226	1.0188224	8.07	‒196,606.2(4.8)	‒46,989.9(1.1)
18	1.0183773	1.0187133	1.0187219	1.0187216	8.06	‒196,586.8(4.8)	‒46,985.3(1.1)
20	1.0183000	1.0186360	1.0186445	1.0186442	8.06	‒196,571.8(4.8)	‒46,981.7(1.1)
25	1.0180745	1.0184105	1.0184190	1.0184185	8.07	‒196,528.3(4.8)	‒46,971.3(1.1)
28	1.0179195	1.0182554	1.0182639	1.0182634	8.08	‒196,498.4(4.8)	‒46,964.1(1.1)
30	1.0178090	1.0181448	1.0181533	1.0181528	8.08	‒196,477.0(4.8)	‒46,959.0(1.1)
35	1.0175110	1.0178467	1.0178552	1.0178547	8.09	‒196,419.5(4.8)	‒46,945.3(1.1)
40	1.0171880	1.0175236	1.0175323	1.0175317	8.10	‒196,357.2(4.8)	‒46,930.4(1.1)
43.6a	1.0169446	1.0172797	1.0172886	1.0172878	8.11	‒196,310.1(4.8)	‒46,919.2(1.1)