Table 4.
T = 363 K – influence of air relative humidity on CIL decomposition
| |||
---|---|---|---|
Pure CIL (6) | CIL/PVP solid dispersion | CIL/PVP physical mixture | |
RH% | k ± ∆k [1/s] | ||
25.0 % | (3.270 ± 0.241) 10-6 | (9.460 ± 0.822) 10-7 | (9.010 ± 0.664) 10-7 |
50.9 % | (7.922 ± 0.964) 10-6 | (1.522 ± 0.514) 10-6 | (1.555 ± 0.419) 10-6 |
60.5 % | (1.189 ± 0.068) 10-5 | (1.999 ± 0.168) 10-6 | (2.079 ± 0.281) 10-6 |
66.5 % | (1.583 ± 0.143) 10-5 | (2.883 ± 0.467) 10-6 | (2.32 3 ± 0.415) 10-6 |
76.4 % | (1.941 ± 0.106) 10-5 | (3.041 ± 0.143) 10-6 | (3.010 ± 0.331) 10-6 |
linear relationship lnk = f(RH) | |||
a | 0.036 ± 0.006 | 0.024 ± 0.009 | 0.023 ± 0.002 |
sa | 0.002 | 0.002 | 0.0008 |
b | -13.526 ± 0.23 | -14.510 ± 0.57 | -14.520 ± 0.15 |
sb | 0.102 | 0.181 | 0.481 |
r | 0.997 | 0.976 | 0.998 |
The parameters: a, Sa, b, Sb and r were calculated by least square regression and are standing for slope, standard deviation of the slope, intercept, standard deviation of intercept and correlation coefficient, respectively.