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Scope of chiral allylic boronates. The same conditions were used as in Scheme 2. Conversion was determined by analysis of the 19F NMR spectra of the unpurified mixtures. Z:E ratios were determined by GC or 19F NMR analysis (±2%). Yields of purified products (±5%). Enantioselectivity was established by HPLC analysis of the saturated alcohols or corresponding ester derived from boronates (±1%). ds = diastereospecificity. See the Supporting Information for details.
