Fig. 1.

(A) Schematic of the two superlattices formed by ${\mathrm{L}\mathrm{N}\mathrm{F}}_3$ nanoplatelets: hexagonal (light blue) and herringbone (light orange). To highlight the difference in the local arrangement within the superlattices, a reference particle is colored purple, and the different lattice positions are highlighted: primary (green), hexagonal (blue), and herringbone (orange). Note this schematic is for an elongation value $\gamma =1$ for which both tilings fill space. (B) Transformation of a regular hexagon $\left(\alpha =120^{○},\gamma =1\right)$ into an elongated hexagon $\left(\alpha =68^{○},\gamma \right)$. $\gamma$ is the ratio of sides $B$ and $A$, a tunable shape parameter to study the influence of shape on entropic bonds