Scheme 8.
Possible biosynthesis of d6-(E)-β-caryophyllene and d5-α-humulene starting from farnesyl pyrophosphate (FPP) after administration of [5,5-2H2]-1-deoxy-ᴅ-xylulose (d2-DOX) to isolated exocarp of grape berries (Lemberger cultivar).
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