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. 2019 Aug 21;58(17):11689–11698. doi: 10.1021/acs.inorgchem.9b01669

Figure 2.

Figure 2

Evolution in time of the absorption spectra of a solution of [1](PF6)2 in H2O (72 μM) upon irradiation at 298 K with a 443 nm LED (qp = 2.65 × 10–8 mol of photons s–1) under N2, for t = 0–3.5 min (A, Δt = 12 s) and t = 3.5–60 min (B, Δt = 3.2 min), and the time evolution of the absorbance (C) at 413 nm (red), 453 nm (black), and 491 nm (blue) during the first 60 min of irradiation. The vertical dashed line (t = 3.5 min) indicates the completion of the first photosubstitution reaction.