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. 1969 May-Jun;73A(3):299–308. doi: 10.6028/jres.073A.025

Table 8.

Values of pK in ordinary water and in heavy water at the temperature of the minimum pK value

Water Deuterium oxide
tmin pKmin tmin pKmin ΔpKmin
Acetic acid 22.4 4.756 32.0 5.310 0.554
Deuterioacetic acid 22.9 4.771 32.4 5.323 0.552
Phosphoric acid (2nd step) 42.7 7.180 47.7 7.744 0.564
“Self-dissociation” constant 239 11.382 221 12.356 0.974

The temperature of maximum K value (or minimum pK value) is expressed in degrees Celsius. All pK values are on the molality scale.