Table 1.
Instrumental and quantification methods.
| Type | Compound | IS | Quantifier |
Qualifier |
RT |
||||
|---|---|---|---|---|---|---|---|---|---|
| P | F | CE | P | F | CE | (min) | |||
| IS | TCMX | 244 | 209 | 15 | 136 | 75.2 | 15 | 10.8 | |
| AT | PCB8 | TCMX | 222 | 152 | 30 | 152.1 | 151 | 5 | 11.7 |
| AT | α-HCH | TCMX | 216.9 | 181 | 5 | 181 | 145 | 5 | 11.7 |
| AT | HCB | TCMX | 283.9 | 213.9 | 35 | 283.9 | 248.8 | 25 | 11.9 |
| AT | β-HCH | TCMX | 216.9 | 181 | 5 | 181 | 145 | 5 | 12.3 |
| AT | γ-HCH | TCMX | 216.9 | 181 | 5 | 181 | 145 | 5 | 12.4 |
| AT | PCB18 | TCMX | 256 | 186 | 30 | 258 | 186.1 | 30 | 12.6 |
| AT | δ-HCH | TCMX | 216.9 | 181 | 5 | 181 | 145 | 5 | 12.9 |
| AT | PCB28 | TCMX | 256 | 186 | 30 | 258 | 186.1 | 30 | 13.6 |
| AT | Heptachlor | TCMX | 272 | 237 | 25 | 272 | 117 | 40 | 13.9 |
| AT | PCB52 | TCMX | 292 | 220 | 35 | 222 | 150 | 35 | 14.3 |
| AT | Aldrin | TCMX | 262.9 | 192.9 | 40 | 262.9 | 190.9 | 40 | 14.6 |
| AT | PCB44 | TCMX | 292 | 220 | 35 | 222 | 150 | 35 | 14.7 |
| AT | HCEX | TCMX | 352.9 | 262.8 | 25 | 352.9 | 281.9 | 20 | 15.5 |
| AT | PCB66 | TCMX | 292 | 220 | 35 | 220 | 150 | 35 | 15.6 |
| AT | o,p'-DDE | TCMX | 246 | 176.2 | 30 | 248 | 176.2 | 30 | 16.1 |
| AT | PCB101 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 16.2 |
| AT | PCB81 | TCMX | 292 | 220 | 35 | 222 | 150 | 35 | 16.8 |
| AT | p,p'-DDE | TCMX | 246 | 176.2 | 30 | 248 | 176.2 | 30 | 16.8 |
| AT | PCB77 | TCMX | 292 | 220 | 35 | 222 | 150 | 35 | 17.0 |
| AT | o,p'-DDD | TCMX | 235 | 165.2 | 30 | 237 | 165.2 | 20 | 17.0 |
| AT | Endrin | TCMX | 262.9 | 192.9 | 35 | 262.9 | 190.9 | 35 | 17.4 |
| AT | PCB123 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 17.5 |
| AT | PCB118 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 17.6 |
| AT | p,p'-DDD | TCMX | 235 | 165.2 | 30 | 237 | 165.2 | 20 | 17.8 |
| AT | PCB114 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 17.9 |
| AT | o,p'-DDT | TCMX | 235 | 165.2 | 30 | 237 | 165.2 | 20 | 17.9 |
| AT | PCB153 | PCB209 | 360 | 289.9 | 30 | 290 | 218 | 30 | 18.2 |
| AT | PCB105 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 18.3 |
| AT | p,p'-DDT | TCMX | 235 | 165.2 | 30 | 237 | 165.2 | 20 | 18.8 |
| AT | PCB138 | PCB209 | 360 | 289.9 | 30 | 290 | 218 | 30 | 18.9 |
| AT | PCB126 | TCMX | 326 | 255.9 | 35 | 256 | 183.9 | 35 | 19.2 |
| AT | PCB187 | PCB209 | 394 | 324 | 30 | 324 | 254 | 30 | 19.4 |
| AT | PCB167 | PCB209 | 360 | 289.9 | 30 | 290 | 218 | 30 | 19.7 |
| AT | PCB156 | PCB209 | 360 | 289.9 | 30 | 290 | 218 | 30 | 20.3 |
| AT | PCB157 | PCB209 | 360 | 289.9 | 30 | 290 | 218 | 30 | 20.5 |
| AT | PCB170 | PCB209 | 394 | 324 | 30 | 324 | 254 | 30 | 20.8 |
| IS | BDE47 | 498 | 338 | 20 | 496 | 336 | 30 | 20.9 | |
| AT | BDE47 | BDE47 | 486 | 326 | 20 | 484 | 324 | 30 | 20.9 |
| AT | PCB169 | PCB209 | 360 | 290 | 30 | 290 | 218 | 30 | 21.4 |
| AT | PCB180 | PCB209 | 394 | 324 | 30 | 324 | 254 | 30 | 21.7 |
| AT | PCB189 | PCB209 | 394 | 324 | 30 | 324 | 254 | 30 | 22.5 |
| AT | PCB195 | PCB209 | 430 | 360 | 30 | 358 | 288 | 30 | 22.9 |
| IS | BDE99 | 576 | 416 | 20 | 576 | 418 | 20 | 23.5 | |
| AT | BDE99 | BDE99 | 564 | 404 | 20 | 564 | 406 | 20 | 23.5 |
| IS | BDE100 | 576 | 416 | 20 | 576 | 418 | 20 | 24.3 | |
| AT | BDE100 | BDE100 | 564 | 404 | 20 | 564 | 406 | 20 | 24.3 |
| AT | PCB206 | PCB209 | 464 | 392 | 25 | 392 | 322 | 35 | 24.7 |
| IS | PCB209 | 498 | 427 | 30 | 214 | 178 | 20 | 25.6 | |
| IS | BDE153 | 656 | 496 | 20 | 496 | 387 | 40 | 26.4 | |
| AT | BDE153 | BDE153 | 644 | 484 | 20 | 484 | 375 | 40 | 26.4 |
| IS | BDE154 | 656 | 496 | 20 | 496 | 387 | 40 | 27.5 | |
| AT | BDE154 | BDE154 | 644 | 484 | 20 | 484 | 375 | 40 | 27.5 |
AT: Analytical Target compound, IS: internal standard. RT: retention time, P: Parent ion (m/z). F: Fragment ion (m/z).
CE: Collision Energy (eV).