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. 2019 Aug 23;4(11):14458–14465. doi: 10.1021/acsomega.9b01407

Table 2. Solvent Screening in Immobilized BODIPY-Catalyzed Photoarylationa.

graphic file with name ao-2019-014072_0007.jpg

entry solvent yield (%)
1 acetone 59
2 acetonitrile 61
3 ethanol 54
4 DCE 21
5 CH2Cl2 16
6 DMSO 73
7 DMSO 10b
8 DMSO in tracesc
9 DMSO in tracesd
a

A mixture of 4-bromobenzenediazonium tetrafluoroborate (0.25 mmol), immobilized photocatalyst (5 mg, ∼3.6 μmol), and furan (1.0 mL) in solvent (2.0 mL) stirred under green LED at 30 °C for 2 h.

b

Experiment was carried out in the absence of photocatalyst.

c

Experiment was carried out without irradiation.

d

Without irradiation, in the absence of photocatalyst.