Table 1. Chemical composition of the essential oils of M. alternifolia and R. officinalis.
Peak # | Rt | Component | Molecular formula | RIexpa | RIlitb | Content (%) | Identificatione | |
---|---|---|---|---|---|---|---|---|
MAc | ROd | |||||||
1 | 7.43 | α-Thujene | C10H16 | 918 | 918 | 0.77 | - | MS, RI |
2 | 7.63 | α-Pinene | C10H16 | 925 | 925 | 2.55 | 13.94 | MS, RI |
3 | 8.07 | Camphene | C10H16 | 941 | 940 | - | 3.78 | MS, RI |
4 | 8.93 | β-pinene | C10H16 | 972 | 972 | 0.71 | 1.28 | MS, RI |
5 | 9.39 | β-Myrcene | C10H16 | 989 | 989 | 0.63 | 1.12 | MS, RI |
6 | 9.79 | α-Phellandrene | C10H16 | 1003 | 1003 | 0.31 | - | MS, RI |
7 | 10.17 | α-Terpinene | C10H16 | 1015 | 1015 | 10.84 | - | MS, RI |
8 | 10.43 | p-Cymene | C10H14 | 1023 | 1023 | 2.51 | 2.68 | MS, RI |
9 | 10.55 | D-Limonene | C10H16 | 1027 | 1027 | - | 3.01 | MS, RI |
10 | 10.56 | Sylvestrene | C10H16 | 1028 | 1028 | 1.77 | - | MS, RI |
11 | 10.64 | 1,8-Cineole | C10H18O | 1030 | 1030 | 2.88 | 53.67 | MS, RI |
12 | 11.51 | γ-Terpinene | C10H16 | 1058 | 1058 | 23.07 | - | MS, RI |
13 | 12.44 | Terpinolene | C10H16 | 1088 | 1088 | 3.50 | - | MS, RI |
14 | 12.81 | Linalool | C10H18O | 1100 | 1100 | - | 0.86 | MS, RI |
15 | 14.24 | Camphor | C10H16O | 1146 | 1146 | - | 10.43 | MS, RI |
16 | 14.92 | Borneol | C10H18O | 1167 | 1167 | - | 2.58 | MS, RI |
17 | 15.26 | Terpinen-4-ol | C10H18O | 1179 | 1179 | 45.23 | - | MS, RI |
18 | 15.66 | α-Terpineol | C10H18O | 1192 | 1192 | 2.95 | 2.07 | MS, RI |
19 | 22.27 | Caryophyllene | C15H24 | 1424 | 1504 | - | 2.74 | MS, RI |
20 | 22.80 | Alloaromadendrene | C15H24 | 1445 | 1445 | 0.86 | - | MS, RI |
21 | 24.27 | Ledene (Viridiflorene) | C15H24 | 1503 | 1502 | 0.51 | - | MS, RI |
22 | 24.96 | δ-Cadinene | C15H24 | 1530 | 1530 | 0.91 | - | MS, RI |
Monoterpene hydrocarbons | 46.66 | 25.81 | ||||||
Oxygenated monoterpenes | 51.06 | 69.61 | ||||||
Sesquiterpene hydrocarbons | 2.28 | 2.74 | ||||||
Total identified components | 100 | 98.16 |
aRIexp, Retention index determined experimentally on Rtx-5MS column
bRIlit, published retention indices
cMA, Melaleuca alternifolia essential oil
dRO,Rosmarinus officinalis essential oil
eIdentification, was based on comparison of the compounds’ mass spectral data (MS) and retention indices (RI) with those of NIST Mass Spectral Library (2011), Wiley Registry of Mass Spectral Data 8thedition and literature.