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. 2019 Sep 16;10:4220. doi: 10.1038/s41467-019-12223-4

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© The Author(s) 2019

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 6 — Methanol detection in spiked breath. a Response of the methanol detector to breath of an intoxicated volunteer (0.54‰ blood alcohol level) sampled from Tedlar bags. The blue dashed line shows the measurement from the normal breath sample and the red solid line from the spiked sample with 135 ppm methanol, indicating methanol intoxication. The PTR-TOF-MS measurements (with separation column and dilution) of the same samples for b methanol and c ethanol. The instrument shown in c is a PTR-TOF-MS 1000 (Ionicon, Austria) used for sensor validation. Hydrogen (H₂) is not retained by the separation column and does not interfere with the methanol detector