Table 3.
Experimental conditions for the preparation of LCO thin films deposited by the rf-sputtering technique.
Atmosphere a) | Power (W) | Deposition Rate (nm s−1) | Substrate | Substrate Temperature (°C) | Structural/Electrochemical Properties c) | Ref. |
---|---|---|---|---|---|---|
3:1/55/1.0 | 100 | 3.2 | Si (100) wafer | 25 | Influence of the target history and deposition geometry | [51] |
9:3/12/5 | 100 | Si/SiO2/Ti/Pt | 250 | Ta = 700 °C, Qd = 61 µAh cm−2 µm−1; Rc = 74% after 50 cycles | [63] | |
3:1/40/0.5 | 80 | 1.6 | Si/Ti/MgO/Pt | 10 | Ta = 800 °C, Qd = 70 µAh cm−2 µm−1 @ 5 µA cm−2; Rc = 30% over 40 cycles | [64] |
96:4/50/0.5 | 2.75 b) | ~0.3 | Al2O3/Ti/Au | ~110 | Ta = 800 °C, Qd = 60 µAh cm−2 µm−1 @ C/10; Rc = 95% over 100 cycles | [47] |
9:1/-/0.5 | 4.4 b) | Si/Pt and Cu foil | 200 | Ta = 700 °C, Qd = 52 µAh cm−2 µm−1 @ 50 µA | [61] | |
5:1/150/0.2 | 130 | 0.03 | Al foil | 65 | c, Qd = 46 µAh cm−2 µm−1 @ 5 µA cm−2; Rc = 78% over 100 cycles | [65] |
9:1/-/0.5 | 150 | 0.1 | Si/Al/Li2O | 25 | (101)-oriented; Qd = 40 µAh cm−2 µm−1@20 µA cm−2; Rc = 78%@640 µA cm−2 | [48] |
4:1/150/0.27 | 130 | 0.05 | Stainless steel | 25 | Qd = 44 µAh cm−2 µm−1@10 µA cm−2; Rc = 66% after 30 cycles | [66] |
3:1/53/2.2 | 500 | Al foil | 25 | Ta = 500 °C, Qd = 50 µAh cm−2 µm−1@10 µA cm−2; Rc = 80% after 800 cycles | [25] | |
1:0/-/2.0 | 100 | 8.3 | Au | 25 | Kinetics of (104)-plane. DLi ≈ 10−10–10−12 cm2 s−1 | [67] |
2:1/-/0.5 | 200 | Pt wafer | 55 | Power of 200 W, Qd = 61 µAh cm−2 µm−1@20 µA cm−2 | [68] | |
40:1/20/0.14 | 500 | 1 | Quartz/Pt | 300 | Thickness dependence; Qd = 72 µAh cm−2 µm−1@0.1 mA cm−2 | [23] |
3:1/12/2 | 100 | Si/Pt | 25–600 | Ts = 250 °C, Ta = 600 °C, Qd = 50 µAh cm−2 µm−1@10 µA cm−2 | [70] | |
9:1/-/0.5 | 50 | 0.8 | Sapphire/SiO2/Al | 25 | Ta = 500 °C, thermal conductivity 3.7 W m−1 K−1 for Li0.6CoO2 | [71] |
9:3/12/0.5 | 50 | 0.02 | Si/SiO2/Pt | 25 | Ta = 800 °C, Qd = 27 µAh cm−2 µm−1@50 µA cm−2 after 150 cycles | [72] |
a) Composition of the Ar:O2 gas mixture/flow rate in standard cubic centimeter per minute (sccm)/chamber pressure in Pa; b) Specific sputtering power in W cm−2; c) Ta = optimum annealing temperature; Qd = specific discharge capacity; Rc capacity retention.