Table A4.
Hits for the inhibitory activity of HQJZT against IFN-γ production.
| m/z RT | p[1] | po[1] | Origin | Compound | Fragment Ions | Literature |
|---|---|---|---|---|---|---|
| 265.12345_8.988 | −0.0930574 | 0.175785 | FJ | n.i. | ||
| 481.17020_5.056 | −0.0759404 | −0.013529 | RP | Albiflorin * | 503 [M + Na], 197, 151, 133 | [22,23] |
| 415.21121_18.824 | −0.0736124 | 0.0616802 | FJ | n.i. | ||
| 503.15230_5.509 | −0.0722717 | −0.0109856 | RP | Paeoniflorin * [M + Na]+ | 498 [M + NH4], 179, 151, 133 | [22,23] |
| 503.15227_5.348 | −0.0719782 | −0.0112909 | RP | Paeoniflorin * [M + Na]+ | 498 [M + NH4], 179, 151, 133 | [22,23] |
| 498.19688_5.504 | −0.0712826 | −0.0135778 | RP | Paeoniflorin * [M + NH4]+ | 503 [M + Na], 179, 151, 133 | [22,23] |
| 481.17023_4.821 | −0.0650068 | −0.0111313 | RP | Albiflorin * | 503 [M + Na], 197, 151, 133 | [22,23] |
| 714.41099_18.603 | −0.0639971 | 0.0657522 | RZ | n.i. | ||
| 452.32137_22.770 | −0.0626265 | 0.0403574 | FJ | n.i. | ||
| 503.15215_5.060 | −0.0608256 | −0.0112778 | RP | Albiflorin * [M + Na]+ | 498 [M + NH4], 197, 151, 133 | [22,23] |
| 498.19685_5.348 | −0.0600451 | −0.0104305 | RP | Paeoniflorin * | 503 [M + Na], 179, 151, 133 | [22,23] |
| 503.15220_8.397 | −0.0562873 | −0.0109413 | RP | Albiflorin isomer | 219, 197, 133, 105 | [22,23] |
| 282.14928_9.203 | −0.0533495 | 0.0556512 | FJ | n.i. | ||
| 503.15228_4.813 | −0.0531328 | −0.0098537 | RP | Albiflorin * [M + Na]+ | 498 [M + NH4], 197, 151, 133 | [22,23] |
| 438.23858_13.465 | −0.0501564 | 0.0505945 | RZ | n.i. | ||
| 983.31365_5.058 | −0.0496619 | −0.0078355 | RP | Albiflorin * | 503 [M + Na], 481, 197, 151, 133, 105 | [22,23] |
| 379.24752_22.864 | −0.0443945 | 0.0688323 | FJ | n.i. | ||
| 464.24899_9.989 | −0.0438006 | −0.005821 | RP | Pinen-10-yl-ß-vicianoside | 133, 127, 115 | |
| 265.12281_9.203 | −0.0422487 | 0.010489 | RZ | n.i. | ||
| 983.31391_4.812 | −0.040604 | −0.0057421 | RP | Albiflorin * | 503 [M + Na], 481, 197, 151, 133, 105 | [22,23] |
* Identified by comparison with a reference compound; RA = Radix Astragali; RC = Ramulus Cinnamomi; RRGP = Radix et Rhizoma Glycyrrhiza praep cum melle; FJ = Fructus Jujuba, RP = Radix Paeoniae alba; RZ = Rhizoma Zingiberis recens.