Table 3. Structures of the Precipitated, Ordered Phases in Mixtures of Lecithin, Water, and Oleic Acid in Rapeseed Oil Determined by SAXSa.
diffraction
peaks |
|||
---|---|---|---|
sample | order of reflection | q (nm–1) | structure |
W0(3) | 1 | 1.227 | lamellar, d = 5.121 ± 0.001 nm |
2 | 2.454 | ||
3 | 3.682 | ||
W0(13) | 1 (L) | 1.137 | lamellar, d = 5.5242 ± 0.0003 nm |
2 (L) | 2.275 | ||
3 (L) | 3.412 | ||
10 (H) | 0.943 | hexagonal, d = 7.691 ± 0.001 nm | |
11 (H) | 1.634 | ||
20 (H) | 1.887 | ||
W0(40) + O0(13) | 10 | 0.728 | hexagonal, d = 9.95 ± 0.01 nm |
11 | 1.263 | ||
20 | 1.460 | ||
21 | 1.929 | ||
W0(100) + O0(13) | 10 | 0.672 | hexagonal, d = 10.791 ± 0.008 nm |
11 | 1.165 | ||
20 | 1.346 | ||
21 | 1.777 |
The distance d refers to the lamellar period in a lamellar crystal and to the nearest-neighbor distance between cylinders in a hexagonal crystal.