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Carbene insertion reaction kinetics using FeIII-TMPyP4. Reactions conditions were as follows: 83 μM DNA, 30 μM porphyrin, 1 mM styrene, 7 mM EDA, 10 mM Na2S2O4 in reaction buffer (40 mM NH4–HEPES, pH 8.0, 20 mM KCl, 1% DMF, and 0.05% Triton X-100) under anaerobic conditions.
