Electrochemical and photophysical data of compounds 2a–h. PC61BM values were taken from the literature46a.
Compound | λ abs (nm) | E g (eV) | E onset (V) | LUMO (eV) | HOMO (eV) |
---|---|---|---|---|---|
PC61BM | 718 | 1.73 | −0.90 | −3.90 | −5.63 |
2a | 716 | 1.73 | −1.09 | −3.93 | −5.66 |
2b | 718 | 1.73 | −1.08 | −3.94 | −5.67 |
2c | 718 | 1.73 | −1.09 | −3.93 | −5.66 |
2d | 714 | 1.74 | −1.13 | −3.89 | −5.63 |
2e | 720 | 1.72 | −1.07 | −3.95 | −5.67 |
2f | 716 | 1.73 | −1.02 | −4.00 | −5.73 |
2g | 718 | 1.73 | −1.10 | −3.92 | −5.65 |
2h | 718 | 1.73 | −1.09 | −3.93 | −5.66 |
Values obtained using the following formula 45