Table 1.
Entry | Catalyst | Yield (%) |
---|---|---|
1 | PC–I | 64 |
2 | PC–II | 0 |
3 | PC–III | 68 |
4 | PC–IV | 65 |
5 | PC–V | 47 |
6 | PC–VI | 57 |
7 | PC–III | 74b |
8 | PC–III | 85b, c |
9 | PC–III | 85b, c, d |
10 | PC–III | 0e |
11 | – | 0 |
PC photoredox catalyst, DCE 1,2-dichloroethane
aReactions were performed with 1a (0.1 mmol), 2a (0.3 mmol), photocatalyst (2 mol%) in 1,2-dichloroethane (0.5 mL), irradiating with 15 W blue LEDs under an air atmosphere at room temperature for 16 h. Yields were determined by 1H NMR using 1,1,2,2-tetrachloroethane as internal standard
bUnder O2 atmosphere
cWith 4 Å molecular sieves
d0.2 mol% photoredox catalyst was used
eEither without irradiation or under N2 atmosphere