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. 2019 Sep 25;10:4367. doi: 10.1038/s41467-019-12403-2

Table 1.

Reaction conditions optimizationa

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Entry Catalyst Yield (%)
1 PC–I 64
2 PC–II 0
3 PC–III 68
4 PC–IV 65
5 PC–V 47
6 PC–VI 57
7 PC–III 74b
8 PC–III 85b, c
9 PC–III 85b, c, d
10 PC–III 0e
11 0
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PC photoredox catalyst, DCE 1,2-dichloroethane

aReactions were performed with 1a (0.1 mmol), 2a (0.3 mmol), photocatalyst (2 mol%) in 1,2-dichloroethane (0.5 mL), irradiating with 15 W blue LEDs under an air atmosphere at room temperature for 16 h. Yields were determined by 1H NMR using 1,1,2,2-tetrachloroethane as internal standard

bUnder O2 atmosphere

cWith 4 Å molecular sieves

d0.2  mol% photoredox catalyst was used

eEither without irradiation or under N2 atmosphere