Table 1. Quantum Yields (Φt-c) and Photoisomerization Rate Constants (kiso, s–1) of H2L and [Ln2L3(DMSO)4] Complexes in Different Solvents.
| ethanol |
acetonitrile |
|||
|---|---|---|---|---|
| compounds | 103Φt→c | 104kiso | 103Φt→c | 104kiso |
| H2L | 41.1 ± 0.45 | 88.7 ± 5.7 | 22.7 ± 0.26 | 70.1 ± 5.3 |
| [Eu2(L)3(DMSO)4] | 7.07 ± 0.26 | 69.1 ± 2.3 | 6.82 ± 0.34 | 63.5 ± 3.1 |
| [Gd2(L)3(DMSO)4] | 5.80 ± 0.32 | 65.0 ± 3.6 | 4.30 ± 0.29 | 74.3 ± 4.1 |
| [Tb2(L)3(DMSO)4] | 6.37 ± 0.39 | 79.3 ± 4.2 | 6.16 ± 0.42 | 81.0 ± 5.1 |