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. 2019 Sep 9;4(13):15530–15538. doi: 10.1021/acsomega.9b01817

Table 1. Quantum Yields (Φt-c) and Photoisomerization Rate Constants (kiso, s–1) of H2L and [Ln2L3(DMSO)4] Complexes in Different Solvents.

  ethanol
acetonitrile
compounds 103Φt→c 104kiso 103Φt→c 104kiso
H2L 41.1 ± 0.45 88.7 ± 5.7 22.7 ± 0.26 70.1 ± 5.3
[Eu2(L)3(DMSO)4] 7.07 ± 0.26 69.1 ± 2.3 6.82 ± 0.34 63.5 ± 3.1
[Gd2(L)3(DMSO)4] 5.80 ± 0.32 65.0 ± 3.6 4.30 ± 0.29 74.3 ± 4.1
[Tb2(L)3(DMSO)4] 6.37 ± 0.39 79.3 ± 4.2 6.16 ± 0.42 81.0 ± 5.1