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. 2019 Sep 11;4(13):15364–15372. doi: 10.1021/acsomega.9b01255

Table 3. Method Accuracy and Precisiona.

    pool A
pool B
pool C
pool D
    interday intraday interday intraday interday intraday interday intraday
TPrP measured 16.5 17.1 41.4 42.3 102 110 246 244
  accuracy 103 107 103 106 102 110 98.3 98
  RSD % 2.4 5 2.8 4 1.6 7.1 1.2 1.8
TPhP measured 18.4 17.5 40.4 43.5 111 116 264 262
  accuracy 115 109 101 109 111 116 106 105
  RSD % 10.5 6.5 4.3 6.2 7.8 11 3.9 3.5
TnBP measured 15.3 16.9 39.9 41.6 102 103 246 238
  accuracy 96 106 100 104 102 103 99 95
  RSD % 2.4 3.9 2.1 2.8 1.3 2.3 1 3.4
TEP measured 14.7 16.6 40.5 40.2 99 97 248 244
  accuracy 92 104 101 101 99 97 99 98
  RSD % 3.1 2.7 0.6 0.3 0.7 2.1 0.7 1.6
TEHP measured 17.3 18.2 36.1 42.4 86 103 271 224
  accuracy 108 114 90 106 86 103 108 90
  RSD % 8.7 9.8 11 4.2 9.7 6 5.8 7.4
TDCPP measured 18.1 13.7 44.5 46 88 86 239 240
  accuracy 113 86 111 115 88 86 96 96
  RSD % 9.3 10 9.8 11 8.2 9.9 3.1 2.9
TDBPP measured 13.8 14.8 38 34.2 93 88 246 256
  accuracy 87 93 95 86 93 88 98 102
  RSD % 9.5 5.2 6.8 10.2 4.8 8.6 1.1 1.6
TCPP measured 16.1 16.4 38.8 42.4 103 103 246 242
  accuracy 100 102 97 106 103 103 99 97
  RSD % 0.2 1.6 3.8 4.2 2.2 1.8 1 2.4
TCP measured 16.6 16.5 42.8 43.5 103 100 254 241
  accuracy 104 103 107 109 103 100 101 97
  RSD % 2.8 2.3 4.6 6.1 1.8 0.1 1 2.5
TCEP measured 15.7 16.6 40.6 41.5 102 97 250 232
  accuracy 98.3 104 102 104 102 97 100 93
  RSD % 1.2 2.5 1.8 2.7 1.3 1.9 0.1 5.2
TBOEP measured 18.4 17.6 32.3 37.8 100 97 218 230
  accuracy 115 110 80.7 94.4 100 97 87 92
  RSD % 10.4 6.9 9.1 4 0.3 2.2 9.2 5.8
RDP measured 13.8 14.6 32.4 34.7 90 88 246 225
  accuracy 86 91 81 87 90 88 98 90
  RSD % 9.8 6.2 9.6 9.3 7.4 8.6 1.2 7.1
EHDPP measured 17.8 18.1 43.9 44.7 88 108 243 280
  accuracy 111 113 110 112 88 108 97 112
  RSD % 12.2 9.4 6.3 8.3 8.5 5.3 2 8.5
DAP measured 17.2 17.2 40.8 42.6 105 108 241 231
  accuracy 108 108 102 107 105 108 97 92
  RSD % 5.4 5.4 3.1 4.6 3.4 5.4 2.5 5.5
DMP measured 15.9 15.3 39.2 38.9 97 97 242 241
  accuracy 99.5 95.7 97.9 97.1 97 97 97 96
  RSD % 0.3 3 1.5 2 1.8 1.8 2.3 2.6
DHP measured 17.2 17.5 40.3 40.4 102 102 246 229
  accuracy 107 109 101 101 102 102 98 92
  RSD % 5.1 6.4 0.6 0.8 1.4 1.3 1.2 5.9
DEP measured 18.9 19.3 42.1 41.7 109 99 246 248
  accuracy 118 121 105 104 109 99 98 99
  RSD % 12.6 14.7 2.8 3 6.2 0.5 1.2 0.5
DBP measured 17.7 14.1 31.9 44.7 118 92 261 241
  accuracy 111 88.4 79.8 112 118 92 104 97
  RSD % 7.6 8.2 13.3 8.4 12.9 5.8 3.1 2.4
BBP measured 14.6 14.7 35 35.4 97 95 260 241
  accuracy 90.9 91.9 87.4 88.4 97 95 104 96
  RSD % 6.4 5.7 7 8.2 1.9 3.3 2.8 2.5
TBBPA measured 14.3 15.4 36.4 40.5 90 110 238 227
  accuracy 89.5 96.0 90.9 101 90 110 95 91
  RSD % 7.4 2.8 4.8 1 7 7.1 3.3 6.5
a

Concentrations for the pools A, B, C, and D are 16, 40, 100, and 250 ng/mL, respectively.