Table 1. Photophysical data of PX/CB[6].

Compound	EX (nm)	λ Fluo (nm)	λ Phos (nm)	τ Fluo (ns)	τ Phos (ms)	Φ Fluo (%)	Φ Phos (%)	K Fluo r a (s–1)	K Fluo nr b (s–1)	K isc c (s–1)	K Phos r d (s–1)	K Phos nr e (s–1)
PBC/CB[6]	366	427	510	8.40	2620	17.3	9.7	2.1 × 107	8.7 × 107	1.2 × 107	3.7 × 10–2	0.34
PFC/CB[6]	330	434	520	5.61	0.0095	27.7	1.9	4.9 × 107	1.2 × 108	1.4 × 107	2.0 × 103	1.0 × 105
PCC/CB[6]	370	420	500	2.52	275	41.8	26.7	1.6 × 108	1.2 × 108	1.1 × 108	0.97	2.7
PYCl/CB[6]	334	388	500	3.62	5.40	3.7	81.2	1.0 × 107	4.2 × 107	2.2 × 108	150	34.8
PIC/CB[6]	407	477	575	1.53	1.40	2.6	3.9	1.7 × 107	6.1 × 108	2.5 × 107	27.9	6.9 × 102
PEC/CB[6]	429	494	— f	7.52	— f	4.34	— f	5.8 × 106	1.3 × 108	— g	— g	— g
PC/CB[6]	250	494	— f	23.14	— f	2.60	— f	1.1 × 106	4.2 × 107	— g	— g	— g

^aThe radiative decay rate constant of fluorescence KFluor = Φ_Fluo/τ_Fluo.

^bThe nonradiative decay rate constant of fluorescence KFluonr = (1 – Φ_Fluo – Φ_Phos)/τ_Fluo.

^cThe intersystem crossing rate constant K_isc = Φ_Phos/τ_Fluo.

^dThe radiative decay rate constant of phosphorescence KPhosr = Φ_Phos/τ_Phos.

^eThe nonradiative decay rate constant of phosphorescence KPhosnr = (1 – Φ_Phos)/τ_Phos.

^fNot detected.

^gNot calculated.