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Scope of the 1,3‐aminothiolation with respect to various D–A cyclopropanes 2. Reaction conditions: 1 (220 μmol), 2 (200 μmol), 3 a (340 μmol), Sn(OTf)2 (10 mol %), DCE (1.5 mL), 25 °C, 12 h. Yields represent isolated and purified products. DCE=1,2‐dichloroethane.
