. Author manuscript; available in PMC: 2019 Oct 2.

Published in final edited form as: Dalton Trans. 2017 Jul 18;46(28):9118–9125. doi: 10.1039/c7dt01847a

Table 1.

Structural parameters for [(Py₅Me₂)Ru^IIX]ⁿ⁺ complexes stabilized with the hexafluorophosphate counteranion.

	1	2^a	3	3 (OTf)^b	4
Ru−X (Å)	2.097(4)	2.4112(8)	2.158(3)	2.123(1)	2.035(3)
Ru−N_ax (Å)	2.026(4)	2.008(3)	2.001(3)	2.001(1)	2.025(3)
Ru−N_eq (Å)	2.062(4)/	2.074(2)/	2.055(3)/	2.085(1)/	2.073(3)/
	2.072(3)/	2.074(2)/	2.076(3)/	2.062(1)/	2.078(3)/
	2.070(3)/	2.074(2)/	2.087(3)/	2.069(1)/	2.072(3)/
	2.074(4)	2.074(2)	2.065(3)	2.070(1)	2.084(3)
X–Ru−N_ax (°)	177.5(2)	178.98(9)	178.8(1)	178.13(5)	178.3(1)

Data from ref. 47.

Data from ref. 48.