| Crystal data |
| Chemical formula |
C36F30N3O6P3
|
C42H24F18N3O6P3
|
C48H18F36N3O6P3
|
|
M
r
|
1233.30 |
1101.55 |
1509.56 |
| Crystal system, space group |
Monoclinic, P21/c
|
Triclinic, P
|
Triclinic, P
|
| Temperature (K) |
298 |
298 |
298 |
|
a, b, c (Å) |
8.1111 (17), 44.054 (9), 12.259 (2) |
13.4906 (11), 13.6573 (11), 14.9377 (13) |
8.9782 (14), 13.947 (2), 23.205 (4) |
| α, β, γ (°) |
90, 109.612 (12), 90 |
65.253 (2), 68.874 (2), 71.715 (2) |
97.276 (6), 93.155 (6), 91.615 (6) |
|
V (Å3) |
4126.3 (14) |
2288.0 (3) |
2876.2 (8) |
|
Z
|
4 |
2 |
2 |
| Radiation type |
Mo Kα |
Mo Kα |
Mo Kα |
| μ (mm−1) |
0.33 |
0.25 |
0.27 |
| Crystal size (mm) |
0.22 × 0.09 × 0.07 |
0.28 × 0.23 × 0.22 |
0.18 × 0.09 × 0.08 |
| |
| Data collection |
| Diffractometer |
Bruker SMART CCD area detector |
Bruker SMART CCD area detector |
Bruker SMART CCD area detector |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2001 ▸) |
Multi-scan (SADABS; Bruker, 2001 ▸) |
Multi-scan (SADABS; Bruker, 2001 ▸) |
|
T
min, T
max
|
0.736, 0.9 |
0.727, 0.9 |
0.629, 0.9 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
35241, 10189, 6392 |
21657, 11015, 6744 |
28557, 14187, 6133 |
|
R
int
|
0.048 |
0.019 |
0.046 |
| (sin θ/λ)max (Å−1) |
0.667 |
0.666 |
0.675 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.065, 0.153, 1.04 |
0.062, 0.195, 0.98 |
0.063, 0.160, 0.95 |
| No. of reflections |
10189 |
11015 |
14187 |
| No. of parameters |
703 |
817 |
1201 |
| No. of restraints |
0 |
462 |
813 |
| H-atom treatment |
– |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.37, −0.28 |
0.32, −0.27 |
0.28, −0.32 |
