Table 4.
The kinetic parameters for the adsorption of Pb(II) onto SPEN-CTAB-0%.
C0 (mg/L) | Parameters | 50 | 70 | 100 | 150 | 200 |
---|---|---|---|---|---|---|
Pseudo-first-order | k1 (min−1) | 0.0284 | 0.0387 | 0.0450 | 0.0490 | 0.0201 |
qe (cal.) (mg/g) | 13.861 | 13.730 | 13.821 | 13.052 | 12.174 | |
qe (exp.) (mg/g) | 195.82 | 196.09 | 202.99 | 217.92 | 246.96 | |
R 2 | 0.9370 | 0.9588 | 0.9712 | 0.8994 | 0.4650 | |
Pseudo-second-order | k2 (g/mg·min) | 1.8 × 10−4 | 3.4 × 10−4 | 3.8 × 10−4 | 8.1 × 10−4 | 1.1 × 10−3 |
qe (cal.) (mg/g) | 234.74 | 219.30 | 225.22 | 228.83 | 245.70 | |
qe (exp.) (mg/g) | 195.82 | 196.09 | 202.99 | 217.92 | 246.96 | |
R 2 | 0.9896 | 0.9975 | 0.9978 | 0.9990 | 0.9951 | |
Intraparticle diffusion | k i1 | 23.188 | 28.463 | 31.556 | 44.485 | 55.225 |
C | −5.5100 | −1.8826 | −2.4937 | −0.9429 | 10.448 | |
R 1 2 | 0.8930 | 0.9875 | 0.9877 | 0.9967 | 0.9446 | |
k i2 | 8.5084 | 5.5405 | 4.7350 | 2.1192 | 2.2246 | |
C | 101.91 | 136.41 | 153.10 | 195.22 | 197.36 | |
R 2 2 | 0.9668 | 0.9819 | 0.9545 | 0.9806 | 0.3939 |