Table 2. High Resolution of O 1s Core-Level Values for the (a) Undoped, Co-, Mn-, and Cu-Doped ZnO Nanostructures.
O1 |
O2 |
O3 |
Olattice/Osurface | ||||
---|---|---|---|---|---|---|---|
sample | binding energy (eV) | area (%) | binding energy (eV) | area (%) | binding energy (eV) | area (%) | O1/O2 |
pure ZnO | 528.9 | 17.2 | 530.4 | 12.3 | 532.2 | 1.3 | 1.4 |
ZnO:Co | 528.9 | 14.5 | 530.9 | 14.2 | 532.9 | 2.7 | 0.9 |
ZnO:Mn | 529.8 | 21.3 | 531.3 | 13.1 | 532.8 | 1.2 | 1.6 |
ZnO:Cu | 529.0 | 20.4 | 530.9 | 12.6 | 532.9 | 1.2 | 1.6 |