Table 1.
Sugar residue | H-1 C-1 | H-2 C-2 | H-3 C-3 | H-4 C-4 | H-5 (5a,b) C-5 | H-6 C-6 |
---|---|---|---|---|---|---|
Repeat unit | ||||||
→2)-β-d-Ribf-(1→ | ||||||
A | 5.35 | 4.22 | 4.44 | 4.07 | 3.87, 3.71 | |
108.2 | 81.9 | 71.0 | 83.8 | 63.0 | ||
→3)-α-d-Rhap-(1→ | ||||||
B | 5.06 | 4.24 | 3.91 | 3.53 | 3.90 | 1.31 |
103.3 | 71.1 | 79.9 | 72.3 | 70.4 | 18.0 | |
→3)-α-d-Rhap-(1→ | ||||||
C | 4.98 | 4.18 | 3.85 | 3.57 | 3.80 | 1.29 |
103.2 | 71.1 | 79.4 | 72.5 | 70.7 | 17.9 | |
→2)-α-d-Rhap-(1→ | ||||||
D | 5.15 | 4.10 | 3.93 | 3.53 | 3.76 | 1.32 |
100.9 | 79.3 | 71.0 | 73.4 | 70.7 | 18.0 | |
Non-reducing enda | ||||||
→3)-α-d-Rhap-(1→ | ||||||
B′ | 5.09 | 4.27 | 4.29 | 3.60 | 3.90 | 1.31 |
103.2 | 70.7 | 76.7 | 72.2 | 70.4 | 18.0 |
a The signals for the methylphosphate group are at δH 3.63, δC 54.3, and δP 1.75.