. Author manuscript; available in PMC: 2020 Oct 21.

Published in final edited form as: Inorg Chem. 2019 May 24;58(20):13631–13638. doi: 10.1021/acs.inorgchem.9b00965

TABLE 2.

Selected bond distances (Å) and angles (deg) describing the Cu(I)-coordination environment in the crystal structures of [Cu(I)phenPS]BF₄•CH₃CN (8) and [Cu(I)naphPS] BF₄•CH₃CN (9).

Parameter	8	9
Cu(1)-P(1)	2.2870(7)	2.2324(9)
Cu(1)-P(4)	2.2669(7)	2.2672(9)
Cu(1)-S(1)	2.3220(7)	2.3475(9)
Cu(1)-S(3)	2.3042(7)	2.3219(9)
P(1)^•••P(4)	3.2343(10)	3.3426(9)
P(1)-Cu(1)-P(4)	90.51(3)	95.95(3)
S(1)-Cu(1)-S(3)	121.98(3)	109.72(3)
P(1)-C(7)-C(12)	119.16(19)	125.2(2)
P(1)-C(1)-P(2)	112.60(14)	114.45(16)
C(1)-P(2)-S(1)	110.48(9)	112.35(11)
P(1)-C(7)^•••C(16)-P(4)	10.8(3)	22.21(17)