Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Palladium-accelerated back-isomerization of Z-1. a) Kinetics of the thermal back-isomerization of Z-1 (c = 0.187 mM) in the presence of increasing concentrations of 2 (A∞ denotes the absorbance at λmax before irradiation; A0 – immediately after exposure to UV light; At – after thermal relaxation for time t). b) Cage concentration dependence of the pseudo-first-order rate constant kobs. c) The proposed mechanism underlying the Pd2+-accelerated back-isomerization of Z-1.
