Table 3. Crystallographic Data of the Pyrrolylimines 6e–g and Pyrrolo[2,3-c]Isoquinolines 8b and 8c.
| compound | 6e | 6f | 6g | 8b | 8c |
|---|---|---|---|---|---|
| chemical formula | C17H19N3O | C28H26N4 | C16H16FN3 | C22H19N3 | C22H17Cl2N3 |
| Mr | 281.35 | 418.53 | 269.32 | 325.40 | 394.28 |
| crystal system/space group | triclinic/P1̅ | monoclinic/P21/c | monoclinic/P21/c | orthorhombic/Pna21 | triclinic/P1̅ |
| a, b, c (Å) | 6.5117(9), 10.8618(15), 12.3586(14) | 9.813(2), 25.305(4), 9.7316(11) | 8.8167(10), 17.559(2), 9.4619(9) | 8.8186(12), 10.9933(15), 18.078(2) | 8.4643(7), 9.8411(8), 12.2281(6) |
| α, β, γ (°) | 107.350(11), 96.512(11), 106.366(13) | 90.0, 101.981(14), 90.0 | 90.0, 90.43(1), 90.0 | 90.0, 90.0, 90.0 | 97.028(6), 98.958(6), 96.320(7) |
| V (Å3) | 781.70(19) | 2363.9(7) | 1464.8(3) | 1752.6(4) | 989.90(13) |
| Z | 2 | 4 | 4 | 4 | 2 |
| μ (mm–1) | 0.08 | 0.07 | 0.08 | 0.07 | 0.34 |
| crystal size (mm) | 0.31 × 0.25 × 0.19 | 0.23 × 0.17 × 0.14 | 0.21 × 0.15 × 0.15 | 0.21 × 0.16 × 0.15 | 0.25 × 0.20 × 0.19 |