Scheme 33.

Photoinduced difluoroalkylation of N‐phenylcinnamamides (138, 140) for the regioselective synthesis of difluoroalkylated quinoline‐2‐ones (6‐endo cyclization) (139) and 1‐azaspiro[4.5]decanes (5‐exo cyclization/dearomatization) (141).

Photoinduced difluoroalkylation of N‐phenylcinnamamides (138, 140) for the regioselective synthesis of difluoroalkylated quinoline‐2‐ones (6‐endo cyclization) (139) and 1‐azaspiro[4.5]decanes (5‐exo cyclization/dearomatization) (141).