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. Author manuscript; available in PMC: 2019 Oct 25.
Published in final edited form as: J Phys Chem. 1996 Jun 13;100(24):10135–10144. doi: 10.1021/jp950941b

TABLE 1:

Global Analysisa of the Intensity Decay of DCS in Ethylene Glycol at 20 °C

wavelength (nm) τ1 = 77 psc τ2 = 1088 psc χR2
α1(λ) f1b(λ) α2(λ) f2(λ)
480 0.680 0.130 0.320 0.870 1.5b (176.9)d
500 0.466 0.058 0.534 0.942
520 0.308 0.030 0.692 0.970
540 0.000 0.000 1.000 1.000
560 −0.043 −0.003 0.957 0.997
580 −0.135 −0.011 0.865 0.989
600 −0.294 −0.028 0.706 0.972
a

The χR2 values were calculated using δφ = 0.3° and δm = 0.007, as the uncertainties in the phase and modulation, respectively.

b

The value of fi(λ) describes the fractional steady state intensity at each wavelength λ and is given by fi(λ) = αi(λ)τi/Σαj(λ)τj.

c

Decay times from the global analysis for all wavelengths.

d

The χR2 values are for global analysis of the data at all emission wavelengths. The number in parentheses is the χR2 value obtained for the single decay time fit, and the value of 1.5 is for the global two decay time fit.