Table 2. Unique rings of 1a mok network.
No. | Cyclobutane | Overall type† | Donor type | Acceptor type |
---|---|---|---|---|
Six-membered rings | ||||
Primary | ||||
1 | CB2 | DD | syn, anti | – |
2 | CB1 | DA | anti | 3-acceptor |
3 | CB2 | DA | syn | 3-acceptor |
4 | CB1 | DA | anti | 4-acceptor |
5 | CB2 | DA | anti | 4-acceptor |
6 | CB1 | AA | – | 3,4-acceptor |
Secondary | ||||
7 | CB1 | DD | anti/gauche | – |
8 | CB2 | DA | anti | 4-acceptor |
9 | CB1 | DA | gauche | 4-acceptor |
10 | CB2 | DA | anti | 3-acceptor |
11 | CB1 | DA | anti | 3-acceptor |
12 | CB2 | AA | – | 3,4-acceptor |
Eight-membered rings | ||||
1,5 | CB1 | DD | anti, gauche | – |
2,6 | CB2 | DA | syn | 4-acceptor |
3,7 | CB1 | DA | gauche | 3-acceptor |
4,8 | CB2 | AA | – | 3,4-acceptor |
Cyclobutane participation in six- and eight-membered rings as AA = double hydrogen-bond acceptors, DD = double hydrogen-bond donors, or DA = hydrogen-bond donor and acceptor.