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. 2019 Oct 15;24(20):3711. doi: 10.3390/molecules24203711

Table 17.

NMR1H spectra of 17g17k (CDCl3 for g–j and DMSO-d6 for k, δ).

graphic file with name molecules-24-03711-i070.jpg

17g 17h 17i 17j 17k
H-14 s 7.08 s 7.07 s 7.00 s 6.98 s 7.23
H-17 s 7.49 s 7.69 bs 7.98 s 8.13 s 7.26
H-19 s 7.32 s 7.64 bs 7.98 s 8.05 s 7.67
H-22 d 6.76
(J = 8.5 Hz)
m 6.76 d 6.56 (J = 8.0 Hz) d 6.46 (J = 8.1 Hz) d 7.08
(J = 8.4 Hz)
H-23 m 7.40 d 7.51 (J = 8.3 Hz) m 7.34 m 6.84-7.03 d 7.50
(J = 8.4 Hz)
H-24 s 4.04 s 4.99 s 4.11 s 4.19 s 5.27
H-25 s 3.77 s 3.84 s 3.61 bs 3.51 s 3.85
H-26 s 3.29 bs 3.51
H-27 s 1.22 (t-Bu) d 6.88 (J = 2.4 Hz) s 3.48 m 3.85
H-28 m 7.23 s 2.34 (Me)
H-29 m 7.08 m 6.83–6.94 m 6.84–7.03 s 2.40
H-30 s 2.33 (Me) d 7.21
(J = 8.6 Hz)
m 6.83–6.94 m 3.85 (OMe) s 2.59
H-31 m 7.32 d 6.83 (J = 8.5 Hz) m 6.84–7.03
H-32 m 6.83–6.94 m 6.84–7.03
H-33 m 6.83–6.94 m 6.84–7.03
NH bs 9.09 bs 9.56 bs 11.22 bs 11.22 bs 12.28
OH-3 s 18.79 s 18.79 bs 18.7 bs 18.76 bs 18.80
OH-7 --- --- bs 12.64 bs 12.63 bs 12.77
OH-9 s 10.26 s 10.27 s 10.24 s 10.23 s 10.30