Table 17.
№ | 17g | 17h | 17i | 17j | 17k |
---|---|---|---|---|---|
H-14 | s 7.08 | s 7.07 | s 7.00 | s 6.98 | s 7.23 |
H-17 | s 7.49 | s 7.69 | bs 7.98 | s 8.13 | s 7.26 |
H-19 | s 7.32 | s 7.64 | bs 7.98 | s 8.05 | s 7.67 |
H-22 | d 6.76 (J = 8.5 Hz) |
m 6.76 | d 6.56 (J = 8.0 Hz) | d 6.46 (J = 8.1 Hz) | d 7.08 (J = 8.4 Hz) |
H-23 | m 7.40 | d 7.51 (J = 8.3 Hz) | m 7.34 | m 6.84-7.03 | d 7.50 (J = 8.4 Hz) |
H-24 | s 4.04 | s 4.99 | s 4.11 | s 4.19 | s 5.27 |
H-25 | s 3.77 | s 3.84 | s 3.61 | bs 3.51 | s 3.85 |
H-26 | s 3.29 | bs 3.51 | |||
H-27 | s 1.22 (t-Bu) | d 6.88 (J = 2.4 Hz) | s 3.48 | m 3.85 | |
H-28 | m 7.23 | s 2.34 (Me) | |||
H-29 | m 7.08 | m 6.83–6.94 | m 6.84–7.03 | s 2.40 | |
H-30 | s 2.33 (Me) | d 7.21 (J = 8.6 Hz) |
m 6.83–6.94 | m 3.85 (OMe) | s 2.59 |
H-31 | m 7.32 | d 6.83 (J = 8.5 Hz) | m 6.84–7.03 | ||
H-32 | m 6.83–6.94 | m 6.84–7.03 | |||
H-33 | m 6.83–6.94 | m 6.84–7.03 | |||
NH | bs 9.09 | bs 9.56 | bs 11.22 | bs 11.22 | bs 12.28 |
OH-3 | s 18.79 | s 18.79 | bs 18.7 | bs 18.76 | bs 18.80 |
OH-7 | --- | --- | bs 12.64 | bs 12.63 | bs 12.77 |
OH-9 | s 10.26 | s 10.27 | s 10.24 | s 10.23 | s 10.30 |