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(A) Crude venom of the myrmicine ant, Manica rubida, was analyzed by LC-MS on a C18 reversed-phase column with gradient elution (dashed line) using water and acetonitrile supplemented with 0.1% formic acid as mobile phases. The asterisk indicates the peptide that was isolated for further characterization. (B) The mass spectrum of the corresponding decapeptide U-MYRTX-MANr1 acquired on a high-resolution micrOTOF-QII instrument (Bruker Daltonics, Billerica, MA, USA).
